无机化学与功能材料 Inorganic Chemistry and Functional Materials
章慧课题组: 配位立体化学与圆二色光谱

Hui ZHANG — Stereochemistry

Selected Publications

  1. Hui Zhang. Coordination Chemistry—Principles and Applications. Beijing: Chemical Industry Press. 2009.
  2. Hui Zhang et al. Experiment 18, 19, 23, 36, 40 and 42 in Wang Z B ed. Comprehensive Experiments in Chemistry. 2nd, Beijing: Science Press. 2007.
  3. Hui Zhang et al. Experiment 24, 25, 26, 27, 30, 33, 50 and 52 in Wang Z B ed. Comprehensive Experiments in Chemistry. Beijing: Science Press. 2003.

  1. Shi-Gang Wan, Li-Rong Lin, Li-Li Zeng, Yi-Ji Lin, Hui Zhang. Efficient optical resolution of water-soluble self-assembled tetrahedral M4L6 cages with 1,1′-bi-2-naphthol. Chem. Commun., 2014, 50(97): 15301-15304.
  2. 章慧, 颜建新, 吴舒婷, 李丹, 万仕刚, 丁雷, 林丽榕. 对固体圆二色光谱测试方法的再认识—兼谈“浓度效应”. 物理化学学报, 2013, 29(12): 2481-2497. ZHANG Hui, YAN Jian-Xin, WU Shu-Ting, LI Dan, WAN Shi-Gang, DING Lei, LIN Li-Rong. Further Understanding on the Measurement Methods for Solid-State Circular Dichroism Spectroscopy—Discussion on Concentration Effects. Acta Phys. -Chim. Sin., 2013, 29(12): 2481-2497.
  3. 赵檑, 万仕刚, 陈成栋, 林以玑, 方雪明, 章慧. 基于非手性邻苯酚胺衍生物的半醌Fe(III)络合物的镜面对称性破缺及其绝对构型关联. 物理化学学报, 2013, 29(6): 1183-1191. Zhao L, Wan S G, Chen C D, Lin Y J, Fang X M, Zhang H. Mirror Symmetry Breaking and Absolute Configuration Correlations of Fe(III) Complexes with Achiral Substituted o-Iminobenzosemiquinonato Ligands. Acta Phys. -Chim. Sin., 2013, 29(6): 1183-1191.
  4. Xiao Ma, Chen-Sheng Lin, Hui Zhang, Yi-Ji Lin, Sheng-Min Hu, Tian-Lu Sheng and Xin-Tao Wu. Synthesis, spectral and redox switchable cubic NLO properties of chiral dinuclear iron cyanide/isocyanidebridged complexes. Dalton Trans., 2013, 42(34): 12452-12459.
  5. Chun Lin, Wenna Liu, Jun Fan, Yuekui Wang, Shengrun Zheng, Ran Lin, Hui Zhang, Weiguang Zhang, Synthesis of a novel cyclodextrin-derived chiral stationary phase with multiple urea linkages and enantioseparation toward chiral osmabenzene complex. Journal of Chromatography A, 2013, 1283, 68-74.
  6. Lirong Lin, Weizhen Fan, Shui Chen, Jie Ma, Wangxia Hu, Yiji Lin, Hui Zhang, Rongbin Huang. Photochromism of (E)-4-phenyl-1-(pyridine-2-ylmethylene)semicarbazide. New J. Chem., 2012, 36(12): 2562-2567
  7. Meiying Wei, Biao Wu, Lei Zhao, Hui Zhang, Shaoguang Li, Yanxia Zhao, Xiao-Juan Yang. A bis- bisurea receptor with the R,R-cyclohexane-1,2-diamino spacer for phosphate and sulfate ions. Org. Biomol. Chem., 2012, 10(44): 8758-8761.
  8. Yiji Lin, Fang Zou, Shigang Wan, Jie Ouyang, Lirong Lin, Hui Zhang. Dynamic chiral-at-metal stability of tetrakis(d/l-hfc)Ln(III) complexes capped with an alkali metal cation in solution. Dalton Trans., 2012, 41(22): 6696-6706
  9. 章慧, 林丽榕. 配位化学中的镜面对称性破缺. 大学化学, 2012, 27(1): 1-12; 2011, 26(6): 8-15.
  10. 刘成勇, 颜建新, 林以玑, 李丹, 方雪明, 章慧. cis-[Ni(NCS)2tren]的镜面对称性破缺:螯环的特殊手性构象. 物理化学学报, 2012, 28(2): 257-264.
  11. Yiji Lin, Shigang Wan, Fang Zou, Yuekui Wang, Hui Zhang. Structure-chiroptical property relationship of kinetically labile camphor-derivative β-diketone Yb(III) complexes: The adducts coexist as diastereomer or not ? New J. Chem., 2011, 35(11): 2584-2590.
  12. Jian Wang, Lixi Zeng, Dongdong Ding, Xiangjun Li, Hui Zhang, Hong Zhao, Jun Fan, Weiguang Zhang and Yujian He. Studies on the interaction of achiral cationic pseudoisocyanine with chiral metal complexes. Phys. Chem. Chem. Phys., 2011, 13(37): 16741-16747.
  13. Lei Ding, Lirong Lin, Chengyong Liu, Hongkun Li, Anjun Qin, Yan Liu, Ling Song, Hui Zhang, Ben Zhong Tang, and Yufen Zhao. Concentration Effect in Solid-State CD Spectra of Chiral Atropisomeric Compounds. New J. Chem., 2011, 35(9): 1781-1786.
  14. Jian Wang, Chengyong Liu, Dongdong Ding, Lixi Zeng, Qian Cao, Hui Zhang, Hong Zhao, Yimin Yang, Kaixiang Xiang, Yujian He, Guangwei Wang. Aggregation of anionic porphrin with chiral metal complexes and the competitive binding influences of surfactant and polyelectrolyte. New J. Chem., 2011, 35(7): 1424-1432
  15. Ran Lin, Hong Zhang, Shunhua Li, Leiqi Chen, Weiguang Zhang, Ting Bin Wen, Hui Zhang, Haiping Xia. pH-Switchable Inversion of the Metal-Centered Chirality of Metallabenzenes: Opposite Stereodynamics in Reactions of Ruthenabenzene with L- and D-Cysteine. Chem. Eur. J., 2011, 17(8): 2420-2427.
  16. Xiao-Lan Tong, Tong-Liang Hu, Jiong-Peng Zhao, Yue-Kui Wang, Hui Zhang and Xian-He Bu. Chiral magnetic metal-organic frameworks of MnII with achiral tetrazolate-based ligands by spontaneous resolution. Chem. Commun., 2010, (45): 8543-9545.
  17. Guochun Yang, Yunjie Xu, Jianbo Hou, Hui Zhang, and Yufen Zhao. Diastereomers of the Pentacoordinate Chiral Phosphorus Compounds in Solution: Absolute Configurations and Predominant Conformations. Dalton Trans., 2010, 39(30): 6953-6959.
  18. Wu L, Wang J, Zhu C F, lin Y J, Chen L Q, Fan J, Zhang H. Synthesis, characterization, structures and magnetic property of chiral oxalate-bridged dicopper(II) complexes. Science in China Series B: Chemistry, 2010, 53(7): 1255-1260.
  19. Zhao J, Zheng M X, Lin Y J, Chen Y C, Ruan Y P, Zhang H. Inclusion Resolution of 1,1'-Bi-2-naphthol: Crystal Structure and CD Spectroscopy of the Inclusion Complexes. Acta Phys. -Chim. Sin. 2010, 26(7): 1832-1836.
  20. Jian Wang, Dongdong Ding, Lixi Zeng, Qian Cao, Yujian He, Hui Zhang. Transformation, Memorization and Amplification of Chirality in Cationic Co(III) Complexes-Porphyrin Aggregates. New J. Chem., 2010, 34(7): 1394-1400.
  21. Guochun Yang, Yunjie Xu, Jian-Bo Hou, Hui Zhang, Yu-Fen Zhao. Determination of the Absolute Configurations of the Pentacoordinate Chiral Phosphorus Compounds in Solution Using Vibrational Circular Dichroism Spectroscopy and Density Functional Theory. Chem. Eur. J., 2010, 16(8): 2518-2527.
  22. Zhou N, Wan S G, Zhao J, LinY J, Xuan W M, Fang X M, Zhang H. Stereochemistry and solid-state circular dichroism spectroscopy of eight-coordinate chiral lanthanide complexes. Science in China Series B: Chemistry, 2009, 52(11): 1851-1857.
  23. Jian-Bo Hou, Hui Zhang, Jian-Nan Guo, Yan Liu, Peng-Xiang Xu, Yu-Fen Zhao, G. Michael Blackburn. Chirality at phosphorus in pentacoordinate spirophosphoranes: stereochemistry by X-ray structure and spectroscopic analysis. Org. Biomol. Chem., 2009, 7(15): 3020-3023.
  24. Jian-Bo Hou, Guo Tang, Jian-Nan Guo, Yan Liu, Hui Zhang* and Yu-Fen Zhao. Stereochemistry of Chiral Pentacoordinate Spirophosphoranes Correlated with Solid-State Circular Dichroism and 1H NMR Spectroscopy. Tetrahedron: Asymmetry, 2009, 20(11): 1301-1307.
  25. Qing-Xia Yao, Wei-Min Xuan, Chao-Yang Tu, Hui Zhang, Jie Zhang. Self-resolution of a hydrated helix from an achiral zwitterionic salt, spontaneous chiral symmetry breaking in crystallization, and redox chromism behavior of crystals. Chem. Commun., 2009, (1): 59-61.
  26. Lei Ding, Fang Wang, Lei-Qi Chen, Hui Zhang, Yu-Fen Zhao. CD spectroscopy as fingerprint technique on the structural characterization and determination of absolute configurations of unsymmetric chiral Schiff base Ni(II) complexes. Tetrahedron: Asymmetry, 2008, 19(23): 2653-2658.
  27. Wei-Min Xuan, Fang Zou, Lei-Qi Chen, Xue-Ming Fang, Lian Wei, Hui Zhang. Mechanism of absolute asymmetric synthesis and solid-state CD spectroscopy of BPOB. Acta Phys. -Chim. Sin. 2008, 24(6): 955-960.
  28. Xiao-Qing Huang, Wei-Min Xuan, Lei-Qi Chen, Hui Zhang, Jing-Xing Gao. Synthesis, Characterization and solid-state CD spectra of the chiral tetradentate bisferrocenyl ligands. Acta Phys. -Chim. Sin., 2007, 23(12): 1869-1874.
  29. Shu-Ting Wu, Yan-Rong Wu, Qing-Qing Kang, Hui Zhang, La-Sheng Long, Zhiping Zheng, Rong-Bin Huang, Lan-Sun Zheng.Chiral symmetry breaking by chemically manipulating statistical fluctuation in crystallization. Angew. Chem. Int. Ed., 2007, 46(44): 8475-8479.
  30. Fang Wang, Hui Zhang, Li Li, Hong-Qing Hao, Xian-Ying Wang, Jian-Gu Chen. Synthesis and characterization of chiral nickel(II) Schiff base complexes and their CD spectra-absolute configuration correlations. Tetrahedron: Asymmetry, 2006, 17(14): 2059-2063.
  31. Hui Zhang, Yuan-Chuan Chen, Fang Wang, Xiao-Ming Qiu, Li Li, Jian-Gu Chen. Study on solid-state circular dichroism spectroscopy and its application to chiral M(II) Schiff base complexes. Acta Phys. –Chim. Sin., 2006, 22(6): 666-671.
  32. Hui Zhang, Xian-Ying Wang, Lei-Qi Chen, Xue-Ming Fang, Jing-Xing Gao, Zhi-Gu Xu. Studies on absolute asymmetry synthesis and resolution mechanism of chiral cis-bromoammine bis(ethylenediamine)cobalt(III) bromide. Acta Phys. –Chim. Sin., 2006, 22(5): 609-616.

Selected Targets of Current Interest

章慧 教授、博士生导师

学士 (厦门大学,1982)
硕士 (厦门大学,1995)

电话:0592-2183910 (实验室)

研究兴趣:手性化合物的合成、拆分、结构及其立体化学和应用; 手性化合物的溶液和固体CD光谱; 镜面对称性破缺(Mirror Symmetry Breaking)—发现、表征及其应用


Hui ZHANG Professor

B. S., Xiamen University, China, 1982
M. S., Xiamen University, China, 1995 Visiting Scholar, awarded by the British Council Fellowship, University of Exeter, U. K. , 1996-1997

Research Interests:
Synthesis, resolution, and structures of chiral compounds—stereochemistry and applications;
Solution and solid-state CD spectroscopy of chiral compounds; Mirror symmetry breaking— Finding, characterization, and its applications.

E-mail: huizhang@xmu.edu.cn
Department of Chemistry
Xiamen University
Xiamen 361005, Fujian, China
Rm. 246 North Chemistry Building
Tel: ++86-592-2183910 (L)
Fax: ++86-592-2183910