无机化学与功能材料 Inorganic Chemistry and Functional Materials
陶军课题组: 功能配合物与磁性材料

Jun TAO — Molecular Magnetism

Group Members
Associate Professor Yanping Ren (任艳平), Associate Professor Yaxian Zhu (朱亚先), Assistant Professor Xiangjian Kong (孔祥建), Assistant Professor Haixia Zhao (赵海霞)

Selected Publications

  1. “Making spin-crossover crystals by successive polymorphic transformations”, R.-J. Wei, B. Li, J. Tao*, R.-B. Huang, L.-S. Zheng and Z. Zheng*, Inorg. Chem. 2010, 49, in press.
  2. “Temperature-dependent in situ ligand cyclization via C=C coupling and formation of spin-crossover iron (II) coordination polymer”, F.-L. Yang, J. Tao*, R.-B. Huang and L.-S. Zheng, Inorg. Chem. 2010, 49, in press.
  3. “Solvent-Induced Transformation of Single Crystals of a Spin-Crossover (SCO) Compound to Single Crystals with Two Distinct SCO Centers”, B. Li, R.-J. Wei, J. Tao*, R.-B. Huang, L.-S. Zheng and Z. Zheng*, J. Am. Chem. Soc. 2010, 132, 1558-1566.
  4. “Pressure Effects on a Spin-Crossover Monomeric Compound [Fe(pmea)(SCN)2] (pmea = bis[(2-pyridyl)methyl]- 2-(2-pyridyl)ethylamine)”, B. Li, R.-J. Wei, J. Tao*, R.-B. Huang and L.-S. Zheng, Inorg. Chem. 2010, 49, 745–751.
  5. “In Situ C-C Coupling and Formation of a Heptanuclear Copper(II) Cluster”, J.-P. Tong, X.-J. Sun, J. Tao*, R.-B. Huang and L.-S. Zheng, Inorg. Chem. 2010, 49, 1289–1291.
  6. “Self-Assembly of High-Nuclearity Copper Cages: Tricorne Cu21 and Saddlelike Cyclic Cu16”, Y.-L. Bai, V. Tangoulis*, R.-B. Huang, L.-S. Zheng and J. Tao*, Chem. Eur. J. 2009, 15, 2377-2383.
  7. “The designed assembly of augmented diamond networks from predetermined pentanuclear tetrahedral units”, Y.-L. Bai, J. Tao*, R.-B. Huang and L.-S. Zheng, Angew. Chem. Int. Ed. 2008, 47, 5344–5347.
  8. “The effects of pressure on valence tautomeric transitions of dinuclear cobalt complexes”, B. Li, F.-L. Yang, J. Tao*, O. Sato, R.-B. Huang and L.-S. Zheng, Chem. Commun. 2008, 6019–6021.
  9. “Side-effect of ancillary ligand on electron transfer and photodynamics of a dinuclear valence tautomeric complex”, B. Li, J. Tao*, H.-L. Sun, O. Sato*, R.-B. Huang and L.-S. Zheng, Chem. Commun. 2008, 2269–2271.
  10. “Pressure effects and M?ssbauer spectroscopic studies on a 3D mixed-valence iron spin-crossover complex with NiAs topology”, Y.-L. Bai, J. Tao*, R.-B. Huang, L.-S. Zheng, S.-L. Zheng*, K. Oshida and Y. Einaga*, Chem. Commun. 2008, 1753–1755.
  11. “Coexistence of magnetization relaxation and dielectric relaxation in a single-chain magnet”, Y.-L. Bai, J. Tao*, W. Wernsdorfer, O. Sato*, R.-B. Huang and L.-S. Zheng, J. Am. Chem. Soc. 2006, 128, 16428–16429.
  12. “Valence tautomeric transitions with thermal hysteresis around room temperature and photoinduced effects observed in a cobalt-tetraoxolene complex”, J. Tao, H. Maruyama and O. Sato*, J. Am. Chem. Soc. 2006, 128, 1790–1791.
  13. “One-dimensional ferromagnetic complexes built with MnIII3O units”, J. Tao, Y.-Z. Zhang, Y.-L. Bai and O. Sato*, Inorg. Chem. 2006, 45, 4877–4879.
  14. “A three-dimensional coordination polymer featuring effective ferrimagnetic hydroxide-bridged manganese(II) chains”, J.-T. Li, J. Tao*, R.-B. Huang, L.-S. Zheng, T. Yuen, C. L. Lin, P. Varughese and J. Li*, Inorg. Chem. 2005, 44, 4448–4450.
  15. “Synthesis and characterization of a tetrazolate-bridged coordination framework encapsulating D2h-symmetric cyclic (H2O)4 cluster arrays”, J. Tao*, Z.-J. Ma, R.-B. Huang and L.-S. Zheng, Inorg. Chem. 2004, 43, 6133–6135.

Research Interest


陶军 教授、博士生导师

 
博士(中山大学,2001)
硕士(中山大学,1997)
学士(安徽大学,1991)
博士后(日本神奈川科技学院和九州大学)
教育部新世纪优秀人才支持计划(2008)
福建省杰出青年基金(2009)

电话:(0592)2188116 (实验室)
   (0592)2188138 (办公室)
传真:(0592)2183047
电子邮箱:taojun@xmu.edu.cn

研究兴趣:分子磁性的化学与物理调控—光、热、压力与磁性的关系;单分子磁体和单链磁体的合成、磁性与组装;配位聚合物的溶剂热合成、组装与拓扑学。

 




Jun TAO Professor

 
Ph. D. (2001), Sun Yat-Sen (Zhongshan ) University, China;
M.A. (1997), Sun Yat-Sen (Zhongshan ) University, China;
Post-doc (2004-2006), Kanagawa Academy of Science and Technology & Kyushu University, Japan;
B.S. Anhui University, China.

Research Interests: Control of molecular magnetism through chemical and physical stimuli: thermally, pressure-, and light-induced spin-crossover; Synthesis of single-molecule-and single-chain-magnets; Hydrothermal synthesis of functional coordination polymers.