无机化学与功能材料 Inorganic Chemistry and Functional Materials
龙腊生课题组:
多金属簇合物组装;介电\导电\铁电材料合成

La-Sheng LONG —Inorganic Synthesis

Group Members
Associate Professor Yanping Ren (任艳平), Associate Professor Yaxian Zhu (朱亚先), Assistant Professor Xiangjian Kong (孔祥建), Assistant Professor Haixia Zhao (赵海霞)

Selected Publications

  1. “Framework Solids Possessing Both Hydrophobic and Hydrophilic Pores Constructed by Face-sharing Keplerate-type Heterometal-Organic Polyhedra”, X.-J. Kong, H. Zhang, Y.-P. Ren*, L.-S. Long*, Z.-P. Zheng*, R.-B. Huang, L.-S. Zheng, Chem. Eur. J. 2010, 16, 5292–5296.
  2. “Keeping the Ball Rolling-Fullerene-like Molecular Clusters”, X.-J. Kong, L.-S. Long*, Z.-P. Zheng*, R.-B. Huang, L.-S. Zheng, Acc. Chem. Res. 2010, 43, 201-209.
  3. “A Chiral 60-Metal Sodalite Cage Featuring 24 Vertex-sharing [Er4(μ3-OH)4] Cubanes”,X.-J. Kong, Y.-L. Wu, L.-S. Long*, L.-S. Zheng, Z.-P. Zheng*, J. Am. Chem. Soc. 2009, 131, 6918–6919.
  4. “A four-shell, 136-metal 3d-4f heterometallic cluster approximating a rectangular parallelepiped”, X.-J. Kong, L.-S. Long*, R.-B. Huang, L.-S. Zheng, T. D. Harris, Z.-P. Zheng*, Chem. Commun. 2009, 4354–4356..
  5. “Hydrolytic Synthesis and Structural Characterization of Lanthanide Hydroxide Clusters Supported by Nicotinic Acid’, X.-J. Kong, L.-S. Long*, L.-S. Zheng, R.-Y. Wang, Z.-P. Zheng*, Inorg. Chem. 2009, 48, 3268-3273.
  6. “Experimental and theoretical demonstration of ferroelectric anisotropy in a one-dimensional copper(II)-based coordination polymer”, H.-X. Zhao, G.-L. Zhuang, S.-T. Wu, L.-S. Long*, H.-Y. Guo, Z.-G. Ye*, R.-B. Huang*, L. -S. Zheng, Chem. Commun. 2009, 1644–1646.
  7. “Porous Coordination Polymer Crystal Containing One-dimensional Water Chains Exhibiting Guest-Induced Lattice Distortion and Dielectric Anomaly”, H.-B. Cui, B. Zhou, L.-S. Long, Y. Okano, H. Kobayashi*, A. Kobayashi, Angew. Chem. Int. Ed. 2008, 47, 3376–3380.
  8. “A four-shell, nesting doll-like 3d-4f cluster containing 108 metal ions”, X. J. Kong, Y. P. Ren, W. X. Chen, L. S. Long*, Z.-P. Zheng*, R.-B. Huang, L.-S. Zheng, Angew. Chem. Int. Ed. 2008, 47, 2398–2401.
  9. “Dual shell-like magnetic clusters containing Ni-II and Ln(III) (Ln = La, Pr, and Nd) ions”, X.-J. Kong, Y.-P. Ren, L. -S. Long*, Z.-P. Zheng*, G. Nichol, R.-B. Huang, L. S. Zheng, Inorg. Chem. 2008, 47, 2729–2739.
  10. “Interesting Anion-Inclusion Behavior of Cucurbit[5]uril and Its Lanthanide-Capped Molecular Capsule”, J. X. Liu, L. S. Long*, R. B. Huang, L. S. Zheng, Inorg. Chem. 2007, 46, 10168–10173.
  11. “Chiral Symmetry Breaking by Chemically Manipulating Statistical Fluctuation in Crystallization”,S.-T. Wu, Y.-R. Wu, Q.-Q. Kang, H. Zhang, L.-S. Long*, Z.-P. Zheng*, R.-B. Huang, L.-S. Zheng, Angew. Chem. Int. Ed. 2007, 46, 8475–8479.
  12. “A Keplerate magnetic cluster featuring an icosidodecahedron of Ni(II) ions encapsulating a dodecahedron of La(III) ions”, X.-J. Kong, Y.-P. Ren, L.-S. Long*, Z.-P. Zheng*, R.-B. Huang, L.-S. Zheng, J. Am. Chem. Soc. 2007, 129, 7016–7017.
  13. “Construction of polyoxometalates-based coordination polymers through direct incorporation between polyoxometalates and the voids in a 2D network”, X.-J. Kong, Y.-P. Ren, P.-Q. Zheng, Y.-X. Long, L.-S. Long*, R. -B. Huang, L.-S. Zheng, Inorg. Chem. 2006, 45, 10702–10711.
  14. “Influence of steric hindrance of organic ligand on the structure of Keggin-based coordination polymer”, Y.-P. Ren, X.-J. Kong, X.-Y. Hu, M. Sun, L.-S. Long*, R.-B. Huang, L.-S. Zheng, Inorg. Chem. 2006, 45, 4016–4023.
  15. “pH-dependent assembly of Keggin-based supramolecular architecture”, P.-Q. Zheng, Y.-P. Ren, L.-S. Long*, R.-B. Huang, L.-S. Zheng, Inorg. Chem. 2005, 44, 1190-1192.
  16. “A well-resolved uudd cyclic water tetrarner in the crystal host of [Cu(adipate)(4,4-bipyridine)]center dot(H2O)(2)”, L.-S. Long*, Y.-R. Wu, R.-B. Huang, L.-S. Zheng, Inorg. Chem. 2004, 43, 3798-3800.

Selected Results of Current Interest


龙腊生 教授、博士生导师

 
博士(中山大学,1999)
硕士(兰州大学,1989)
学士(安徽师范大学,1986)

国家杰出青年科学基金。

电话:(0592)2189638 (实验室)
   (0592)2189682 (实验室)
传真:(0592)2183047
电子邮箱:lslong@xmu.edu.cn

研究兴趣:多金属簇合物组装,介电,导电和铁电材料的合成。

 




La-Sheng LONG Professor

 
Ph.D. 1999, Zhongshan University.
M.S. 1989, Lanzhoun University;
B.S. 1986, Anhui Normal University;

Research Interests:Assembly of multinuclear metal clusters; Synthesis of dielectric, electric and ferroelectric materials

Honors and Awards:
2008 National Scientific Fund for Distinguished Young Investigator