张弘

最新更新日期:2018-5-8 8:43:24     浏览次数:8477次     
厦门大学化学系卢嘉锡楼742室
电话/传真:0086-592-2186698
E-mail: zh@xmu.edu.cn
课题组网页:http://hpxia.xmu.edu.cn/
更新个人信息
个人简历:
1997.09-2001.07 厦门大学化学化工学院材料科学与工程系,学士
2001.09-2007.08 厦门大学化学化工学院化学系,博士
2007.08-2011.09 厦门大学化学化工学院化学系,助理教授
2012.04-2013.04 香港科技大学化学系,访问学者
2011.09-至今 厦门大学化学化工学院化学系,副教授
研究兴趣:
经典有机反应的拓展研究及导向有机合成的金属有机化学研究
近期主要代表论著:

1.      X. Zhou, H. Zhang,* Chem. - Eur. J. 2018. Reactions of Metal-Carbon Bonds within Six-Membered Metallaaromatic Rings.

2.      X. Zhou, F. Huang, C. Tang, Q. Zhuo, Z. Chen, H. Zhang,* H. Xia, Chem. Commun. 2018, 54, 4009-4012. A missing member of conjugated N-heterocycles: realizing pyrido[1,2-α]azepine by reacting ruthenium alkenylcarbene complex with alkyne.

3.      Y. Hua, H. Zhang,* H. Xia,* Youji Huaxue 2018, 38, 11-28. Aromaticity: History and Development.

4.      Q. Zhuo, J. Lin, Y. Hua, X. Zhou, Y. Shao, S. Chen, Z. Chen, J. Zhu, H. Zhang, H. Xia,* Nat Commun 2017, 8, 1912. Multiyne chains chelating osmium via three metal-carbon sigma bonds.

5.      L. Long, X. Zhou, T. Wang, Z. Chen, H. Zhang,* H. Xia,* Organometallics 2017, 36, 4184-4190. Synthesis of Imidazopyridinium-Fused Metallacycloallene via One-Pot Reaction of η2-Alkynol-Coordinated Osmacycle with 2-Aminopyridine.

6.      Z.-A. Huang, Q. Lan, Y. Hua, Z. Chen, H. Zhang,* Z. Lin, H. Xia, Organometallics 2017, 36, 4802-4809. Color-Tuning Strategy for Iridapolycycles [(N-N)Ir(C-C)ClPPh3]+ by the Synergistic Modifications on Both the C-C and N-N Units.

7.      M. Luo, L. Long, H. Zhang,* Y. Yang, Y. Hua, G. Liu, Z. Lin,* H. Xia,* J. Am. Chem. Soc. 2017, 139, 1822-1825. Reactions of Isocyanides with Metal Carbyne Complexes: Isolation and Characterization of Metallacyclopropenimine Intermediates.

8.      J. Chen, Z.-A. Huang, Z. Lu, H. Zhang,* H. Xia,* Chem. Eur. J. 2016, 22, 5363-5375. Synthesis of Cyclic Vinylidene Complexes and Azavinylidene Complexes by Formal [4+2] Cyclization Reactions.

9.      Q. Zhuo, X. Zhou, H. Kang, Z. Chen, Y. Yang, F. Han, H. Zhang,* H. Xia,* Organometallics 2016, 35, 1497-1504. Synthesis of Fused Metallaaromatics via Intramolecular C–H Activation of Thiophenes.

10.  Q. Zhuo, Z. Chen, Y. Yang, X. Zhou, F. Han, J. Zhu, H. Zhang,* H. Xia,* Dalton Trans. 2016, 45, 913-917. Synthesis of aromatic ruthenabenzothiophenes via C-H activation of thiophenes.

11.  M. Luo, C. Zhu, L. Chen, H. Zhang,* H. Xia,* Chemical Science, 2016, 7, 1815-1818. Halogenation of carbyne complexes: isolation of unsaturated metallaiodirenium ion and metallabromirenium ion.

12.  F. Han, J. Li, H. Zhang,* T. Wang, Z. Lin,* H. Xia,* Chem. Eur. J. 2015, 21, 565-567. Reactions of Osmabenzene with Silver/Copper Acetylides: From Metallabenzene to Benzene.

13.  J. Chen, Z.-A. Huang, Y. Hua, H. Zhang,* H. Xia, Organometallics 2015, 34, 340-347. Synthesis of Five-Membered Osmacycles with Osmium–Vinyl Bonds from Hydrido Alkenylcarbyne Complexes.

14.  X. Zhou, X. He, J. Lin, Q. Zhuo, Z. Chen, H. Zhang,* J. Wang, H. Xia,* Organometallics 2015, 34, 1742-1750. Reactions of Osmium Hydrido Alkenylcarbyne with Allenoates: Insertion and [3 + 2] Annulation.

15.  Y. Wei, X. Zhou, G. Hong, Z. Chen, H. Zhang,* H. Xia,* Organic Chemistry Frontiers 2015, 2, 560-568. Reactions of osmapyridinium with terminal alkynes.

16.  T. Wang, F. Han, H. Huang, J. Li, H. Zhang,* J. Zhu, Z. Lin,* H. Xia,* Sci. Rep. 2015, 5, 9584. Synthesis of Aromatic Aza-metallapentalenes from Metallabenzene via Sequential Ring Contraction/Annulation.

17.  F. Han, T. Wang, J. Li, H. Zhang,* H. Xia,* Chem. Eur. J. 2014, 20, 4363-4372. m-Metallaphenol: Synthesis and Reactivity Studies.

18.  H. Zhang,* R. Lin, J. Li, J. Zhu, H. Xia, Organometallics 2014, 33, 5606-5609. Interconversion between Ruthenacyclohexadiene and Ruthenabenzene: A Combined Experimental and Theoretical Study

19.  Q. Zhuo, T. Wang, X. Zhou, H. Zhang,* Chin. J. Org. Chem. 2014, 34, 1471-1486. Progresses of Ring Expansion Reaction of Small Transitional Metallacyclic Compounds.

20.  T. Wang, J. Zhu, F. Han, C. Zhou, H. Chen, H. Zhang,* H. Xia,* Angew. Chem., Int. Ed. 2013, 52, 13361-13364. Synthesis of Five-Membered Osmacycloallenes and Conversion into Six-Membered Osmacycloallenes.

21.  T. Wang, H. Zhang,(Co-first authors) F. Han, L. Long, Z. Lin,* H. Xia,* Angew. Chem., Int. Ed. 2013, 52, 9251-9255. Key Intermediates of Iodine-Mediated Electrophilic Cyclization: Isolation and Characterization in an Osmabenzene System.

22.  T. Wang, H. Zhang, (Co-first authors) F. Han, L. Long, Z. Lin,* H. Xia,* Chem. Eur. J. 2013, 19, 10982-10991. cine-Substitution Reactions of Metallabenzenes: An Experimental and Computational Study.

23.  J. Chen, C. Zhang, T. Xie, T. B. Wen, H. Zhang,* H. Xia,* Organometallics 2013, 32, 3993-4001. Conversion of a Hydrido–Butenylcarbyne Complex to η2-Allene-Coordinated Complexes and Metallabenzenes.

24.  C. Zhang, H. Zhang, L. Zhang, T. B. Wen, X. He,* H. Xia,* Organometallics 2013, 32, 3738-3743. Mechanistic Study of Indolizine Heterocycle Formation by Ruthenium(II)-Assisted Three-Component Cross-Coupling/Cyclization.

25.  C. Zhang, H. Zhang, A. Wei, X. He,* H. Xia,* Acta Chim. Sinica 2013, 71, 1373-1378. Synthesis of Ruthena-polycyclic Complexes by Ruthenium-Vinylcarbene Complex.

26.  H. Xie, H. Zhang, Z. Lin,* Organometallics 2013, 32, 2336-2343. DFT Studies on the Palladium-Catalyzed Dearomatization Reaction between Chloromethylnaphthalene and the Cyclic Amine Morpholine.

27.  H. Xie, H. Zhang, Z. Lin,* New J. Chem. 2013, 37, 2856-2861. DFT studies on the mechanisms of palladium-catalyzed intramolecular arylation of a silyl C(sp3)-H bond.

28.   T. Wang, H. Zhang, (Co-first authors) F. Han, R. Lin, Z. Lin,* H. Xia,* Angew. Chem., Int. Ed. 2012, 51, 9838-9841. Synthesis and Characterization of a Metallapyridyne Complex.

29.   R. Lin, J. Zhao, H. Chen, H. Zhang,* H. Xia,* Chem. Asian J. 2012, 7, 1915-1924. Interconversion of Metallabenzenes and Cyclic η2-Allene-Coordinated Complexes.

 


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