Title: Metallaphosphirenes with σ-Aromaticity: Capture of Phosphorus Atom by Metalla-AromaticsAuthors: Xin Yang, Xiaoyan Zhang, Yapeng Cai, Haiping Xia*, Hong Zhang*Abstract: Unsaturated phosphorus heterocycles typically exhibit diminished π-aromaticity. A unique entry into metallaphosphirenes featuring σ-aromat...
Title: Enantioselective Total Synthesis of Bipolarolides A and BAuthors: Yufei Liu, Ke Sun, Qi Wei, Jin Chen, Shengling Sun, Yaxin Li, Zhongkai Feng, Yingying Guo, Zhaohong Lu*Abstract: Bipolarolides A and B are members of the ophiobolin family of sesterterpenes, characterized by their intricate cage-like structures...
Title: Direct Reductive Transformation of Amides: From Methodology Development to Applications in Total SynthesisAuthors: Wei Ou, Pei-Qiang Huang*Abstract: Efficiency, selectivity, versatility, and practicality are major goals in current organic synthesis. Carboxamides are among the most prevalent and versatile func...
Title: Shaping Peptide Assemblies Using Multifaceted Cyclic TectonsAuthors: Chenru Wang, Dexin Lu, Jiakang Li, Linyuan Chen, Xiaobing Zuo, Chuanliu Wu, Xian-Kui Wei, Binju Wang*, Yun-Bao Jiang, Tao Jiang*Abstract: Constructing distinct biomacromolecular assemblies typically necessitates target-specific selection and...
Title: Gram-Scale Total Synthesis of Illisimonin AAuthors: Liangchao Zhu, Jinrui Li, Zhaohong Lu*Abstract: Illisimonin A, a structurally complex sesquiterpenoid isolated from the Illicium genus, possesses a 5/5/5/5/5 pentacyclic scaffold featuring seven contiguous, fully substituted chiral quaternary carbon centers....
Title: Chiral Self-Sorting of Flexible Covalent Organic Pillars forAdaptive Molecular RecognitionAuthors: Shengnan Gao#, Min Zhang#, Yimin Zhang, Congsen Wang, Andrew C.-H. Sue*Abstract: Flexible covalent organic pillars (flex-COP-n) areintroduced as a family of dual-open-ended nanotubular hostsconstructed via dynam...
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