秦瑞轩

个人简历：

教育经历:

2009-2013  本科，中山大学　化学系

2013-2019  博士，厦门大学　化学系（导师：郑南峰 院士，傅钢 教授）

工作经历:

2019-2022  博士后，厦门大学化学化工学院

2022-   副教授，厦门大学化学化工学院（催化科学与工程研究所）

获得荣誉：

中国催化新秀奖, 中国化学会催化委员会（2023）

福建省高层次人才（C类）（2023）

中国博士后科学基金优秀资助博士后, 中国博士后科学基金（2022）

京博科技奖-化学化工与材料京博优秀博士论文奖, 中国化学会-京博控股集团（2020）

科研项目：

福建省自然科学基金-优青项目，氢及其同位素的多相催化精准转化，2024-05 至 2027-04，20万，主持；

国家自然科学基金委员会, 青年科学基金项目, 多相催化加氢促进仲氢诱导超极化, 2023-01-01 至 2025-12-31, 30万元, 主持；

福建省自然科学基金青创项目，多相催化有机液体储氢研究，2023-08 至 2026-07，8万元，主持；

中国博士后科学基金, 特别资助&面上资助, 表界面活性氢物种与单氢加成诱导烯烃异构化反应研究, 2021-06 至 2022-06, 26万元, 主持；

国家自然科学基金委员会，卓越研究群体（原基础科学中心项目），单原子催化，2024-01 至 2027-12，100万元（项目总经费6000万元），参与；

国家重点研发计划，“催化科学”重点专项，甲烷C-H的低温高效催化活化和定向转化，2022-01 至 2026-12，80万元（项目总经费2500万元），参与。

研究兴趣：
氢及其同位素的多相催化转化的实验与理论计算研究：选择性加氢、高效催化加氢/储氢&脱氢/产氢、仲氢诱导超极化、氢同位素标记、氢同位素分离

近期主要代表论著：

1. 1. Q Wu, Y Zhong, L Zhou, M Zhu, S Liu, R Qin*, N Zheng*. Oxygen Vacancy-Enriched Alumina Stabilized Pd Nanocatalysts for Selective Hydrogenation of Phenols. J. Am. Chem. Soc. 2024, 146, 47, 32263–32268.

2. 2. Q Meng, L Liu, D Song, S Wang, R Qin*, G Fu*. Flexible Iron Clusters Promoting Ammonia Synthesis: A Density Functional Theory Prediction. J. Phys. Chem. Lett. 2024, 15, 42, 10623–10628.

3. 3. M Qiao, Q Wu, Y Wang, S Gao, R Qin*, S Liu, K Ding, D Zhao, N Zheng*. Selective hydrogenation catalysis enabled by nanoscale galvanic reactions. Chem, 2024, 10 (11), 3385-3395.

4. 4. Y Wang, X Wang, M Qiao, Q Wu, K Liu, X Yi, R Qin*, G Fu*, N Zheng*. Color center-rich γ-Al₂O₃ promotes propane dehydrogenation. Sci. China Chem. 2024. 67, 4134-4141.

5. 5. P You, L Wu, L Zhou, Y Xu*, R Qin*. Impact of Oxygen-Containing Groups on Pd/C in the Catalytic Hydrogenation of Acetophenone and Phenylacetylene. Catalysts 2024, 14, 545.

6. 6. M Qiao, Y Wang, S Gao, Q Fu, X Wang, R Qin*, N Zheng*. Ligand Modification-Induced Electronic Effects and Synergistic Protic Solvent Effects Promote C═O Bond Hydrogenation. ACS Catal. 2024, 14, 11468–11476.

7. 7. Jing, W.; Mo, S.; Zhang, W.; Zhou, W.; Liu, K.; Wei, J.; Qin, R.*; Zheng, N.* Surface Ligand Evolution: Sulfur-Directed Covalent Bonding of PPh₃ on Pd₄S with Improved Semi-hydrogenation of Terminal Alkynes. Precis. Chem. 2024, 2, 200–207.

8. 8. Wu, Q.^||; Qin R^||; Zhu, M.; Shen, H; Yu, S; Zhong, Y; Fu, G.; Yi, X.*; Zheng, N.* Frustrated Lewis pairs on penta-coordinated Al³⁺-enriched Al₂O₃ promote heterolytic hydrogen activation and hydrogenation. Chem. Sci. 2024, 15, 3140.

9. 9. Qin, R.*; Chen, Z; Wu, Q; Zheng, N; Liu, P.* Supported atomically dispersed Pd catalyzed direct alkoxylation and allylic alkylation. Chin. J. Chem., 2024, 42, 719.

10. 10. Zhang, W.; Qin, R.* Fu, G.; Zheng, N*. Hydrogen Bond Network Induced by Surface Ligands Shifts the Semi-hydrogenation Selectivity over Palladium Catalysts. J. Am. Chem. Soc. 2023. 145, 10178.

11. 11. Mo, S.; Jing, W.; Zhang, W.; Liu, K.; Wu, B.; Qin, R.*; Zheng, N.* Self-reduction synthesis of supported ultrafine Pd nanoparticles for hydrogenation with high activity and stability. Sci. China Mater. 2023. 66, 2708.

12. 12. Liu, K.^||; Qin, R.^||; Li, K.; Zhang, W.; Ruan, P.; Fu, G.*; Zheng, N.* Atomically dispersed palladium catalyzes H/D exchange and isomerization of alkenes via reversible insertion and elimination. Chem Catal. 2021, 1, 1480.

13. 13. Zhang, W.^||; Qin, R.^||; Fu, G.*; Zheng, N.* Heterogenous Isomerization for Stereo-selective Alkyne Hydrogenation to trans-Alkene Mediated by Frustrated Hydrogen Atoms. J. Am. Chem. Soc. 2021, 143, 15882.

14. 14. Li, K^||; Qin, R.^||; Liu, K.;^|| Liu, N.; Zhang, Y.; Liu, S.; Chen, J.; Fu, G.*; Zheng, N.*; Carbon Deposition on Heterogeneous Pt Catalysts Promotes the Selective Hydrogenation of Halogenated Nitroaromatics. ACS Appl. Mater. Interfaces 2021, 13, 52193.

15. 15. Liu, K.^||; Qin, R.^||; Zheng, N.*, Insights into the Interfacial Effects in Heterogeneous Metal Nanocatalysts toward Selective Hydrogenation. J. Am. Chem. Soc. 2021, 143, 83.

16. 16. Qin, R.^||; Zhou, L.^||; Liu, P.; Gong, Y.; Liu, K.; Xu, C.; Zhao, Y.; Gu, L.; Fu, G.*; Zheng, N.* Alkali ions secure hydrides for catalytic hydrogenation. Nat. Catal. 2020, 3, 703.

17. 17. Qin, R.; Deng, G.; Zheng, N.* Assembling Effects of Surface Ligands on Metal Nanomaterials. Prog. Chem. 2020, 32, 1140.

18. 18. Qin, R.; Liu, K.; Wu, Q.; Zheng, N.* Surface Coordination Chemistry of Atomically Dispersed Metal Catalysts. Chem. Rev. 2020, 120, 11810.

19. 19. Qin, R.^||; Wang, P.^||; Liu, P.; Mo, S.; Gong, Y.; Ren, L.; Xu, C.; Liu, K.; Gu, L.; Fu, G.* Zheng, N.* Carbon Monoxide Promotes the Catalytic Hydrogenation on Metal Cluster Catalysts. Research 2020, 4172794.

20. 20. Qin, R.; Zheng, N.* Catalysis Selects Its Own Favorite Facets. Chem 2019, 5, 1935.

21. 21. Liu, K.^||; Qin, R.^||; Zhou, L.; Liu, P.; Zhang, Q.; Jing, W.; Ruan, P.; Gu, L.; Fu, G.*; Zheng, N.* Cu₂O-Supported Atomically Dispersed Pd Catalysts for Semihydrogenation of Terminal Alkynes: Critical Role of Oxide Supports. CCS Chem. 2019, 1, 207.

22. 22. R Qin, P Liu, G Fu, N Zheng*, Strategies for Stabilizing Atomically Dispersed Metal Catalysts. Small Methods 2018, 2 (1), 1700286.

23. 23. Mitchell, S.; Qin, R.; Zheng, N.; Pérez-Ramírez, J., Nanoscale Engineering of Catalytic Materials for Sustainable Technologies. Nat. Nanotechno. 2021, 16, 129.